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Influence of interfacial tension on flow rate and specific consumption of fluorinated foaming agent, containing added ammonium chloride

https://doi.org/10.18322/PVB.2018.27.02-03.93-98

Abstract

In the work, the influence of surface and interfacial tension on the optimum flow rate of an aqueous solution of a fluorinated - foaming agent with the addition of ammonium chloride was determined. Also, the dependence of the time of extinguishing the flame of heptane from the flow rate of foam, obtained from aqueous-salt solution of foaming agent was discovered. Therefore, the dependence of the optimal flow rate and minimum specific foaming agent solution from the value of the coefficient of the spreading of water-salt solution on the surface of heptane’s was defined. It was established that with increasing concentration of the electrolyte (ammonium chloride), surface and interfacial tension is reducing, the fire extinguishing efficiency of the foam is also declining, resulting in increasing of the optimal flow rate of foaming solution and also in increasing of the specific consumption. It is shown that as the interfacial tension decreases, the minimum consumption of the foaming agent and the optimum flow rate of the foam supply increases, and the quench time decreases synchronously. It is determined that with changing of the size of interfacial tension, the curves have a pronounced minimum, which is shifted. It is revealed that the decrease in the ability of the fuel to spread over a solution of foam films leads to an increase in the fire-extinguishing efficiency, which is manifested in a reduction in the minimum specific consumption and the optimum flow rate of supply of the foaming solution.

About the Author

A. I. Melnikov
Национальный исследовательский Московский государственный строительный университет
Russian Federation


References

1. Федунов Р. Г., Рахимова О. С. Влияние межмолекулярных взаимодействий в водных растворах солей на их способность к замерзанию Вестник Волгоградского государственного университета. Серия 1: Математика. Физика.- 2010.-Вып. 13. - С. 89-93.

2. Шароварников А. Ф., Мельников А. И. Эксперементальные исследования огнетушащей способности водных пленкообразующих растворов фторированных поверхностно-активных веществ Пожаровзрывобезопасность Fire and Explosion Safety. - 2015. - Т. 24, № 9. - С. 74-81. DOI: 10.18322PVB.2015.24.09.74-81.

3. Korolchenko D. A., Sharovarnikov A. F. Heat balance of extinguishing process of flammable liquid by sprayed water Advanced Materials Research. - 2014. - Vol. 1070-1072. - P. 1794-1798. DOI: 10.4028www.scientific.netamr.1070-1072.1794.

4. Корольченко Д. А., Шароварников А. Ф. Основные параметры процесса тушения пламени нефтепродуктов пеной низкой кратности Пожаровзрывобезопасность Fire and Explosion Safety.- 2014.- Т. 23, № 7. - С. 65-73.

5. Шароварников А. Ф., Молчанов В. П., Воевода С. С., Шароварников С. А. Тушение пожаров нефти и нефтепродуктов.- М. : Изд. дом “Калан”, 2002. - 448 с.

6. Шрайбер Г., Порст П. Огнетушащие средства. Химико-физические процессы при горении и тушении.- М. : Стройиздат, 1975.- 240 с.

7. Korzeniowski S., Cortina T. Firefighting foams-Reebok redux Industrial Fire Journal.-April 2008. -P. 18-20.

8. Cortina T. The safety & benefits of AFFF agents. Special analysis: Foam Industrial Fire Journal. - June 2007.- P. 70-75.

9. Pabon M., Corpart J. M. Fluorinated surfactants: synthesis, properties, effluent treatment Journal of Fluorine Chemistry.-2002.-Vol. 114, No. 2.-P. 149-156. DOI: 10.1016S0022-1139(02)00038-6.

10. Korolchenko D. A., Sharovarnikov A. F., Byakov A. V. The analysis of oil suppression by aqueous film forming foam through a gas-salt layer of water Advanced Materials Research.-2014.-Vol. 1073-1076.- P. 2353-2357. DOI: 10.4028www.scientific.netamr.1073-1076.2353.

11. Korolchenko D. A., Degaev E. N., Sharovarnikov A. F. Determination of the effectiveness of extinguishing foaming agents in the laboratory 2nd International Conference on Material Engineering and Application (ICMEA 2015).- Wuhan, China : DEStech Publications, Inc., 2015. - P. 17-22.

12. Shaluf I. M., Abdullah S. A. Floating roof storage tank boilover Journal of Loss Prevention in the Process Industries.- 2011.- Vol. 24, Issue 1. - P. 1-7. DOI: 10.1016j.jlp.2010.06.007.

13. Huang Yinsheng, Wencheng Zhang, Dai Xiaojing, Zhao Yu. Study on water-based fire extinguishing agent formulations and properties Procedia Engineering. - 2012. - Vol. 45. - P. 649-654. DOI: 10.1016j.proeng.2012.08.217.

14. Korolchenko D., Tusnin А., Trushina S., Korolchenko A. Physical parameters of high expansion foam used for fire suppression in high-rise buildings International Journal of Applied Engineering Research. - 2015.- Vol. 10, No. 21. - P. 42541-42548.

15. Schaefer T. H., Dlugogorski B. Z., Kennedy E. M. Sealability properties of fluorine-free fire-fighting foams (FfreeF) Fire Technology. - 2007. - Vol. 44, Issue 3. - P. 297-309. DOI: 10.1007s10694-007-0030-8.

16. Дегаев Е. Н., Корольченко Д. А., Шароварников А. Ф. Влияние кратности пен на основные параметры процесса тушения углеводородов Проблемы техносферной безопасности-2015 : матер. 4-й Международной научно-практической конференции молодых ученых и специалистов.-M. : Академия ГПС МЧС России, 2015.- С. 24-28.

17. Kennedy M. J., Conroy M. W., Dougherty J. A., Otto N., Williams B. A., Ananth R., Fleming J. W. Bubble coarsening dynamics in fluorinated and non-fluorinated firefighting foams Colloids and Surfaces A: Physicochemical and Engineering Aspects.-2015.-Vol. 470.-P. 268-279. DOI: 10.1016j.colsurfa. 2015.01.062.

18. Корольченко Д. А., Дегаев Е. Н., Шароварников А. Ф. Горение гептана в модельном резервуаре Пожаровзрывобезопасность Fire and Explosion Safety. -2015. -Т. 24, № 2. -С. 67-70.

19. Zhang Qinglin, Wang Lu, Bi Yixing, Xu Dajun, Zhi Huiqiang, Qiu Peifang. Experimental investigation of foam spread and extinguishment of the large-scale methanol pool fire Journal of Hazardous Materials. -2015.-Vol. 287.-P. 87-92. DOI: 10.1016j.jhazmat.2015.01.017.

20. Шароварников С. А., Корольченко Д. А., Ляпин А. В. Тушение многокомпонентных смесевых топлив фторсинтетическими пенообразователями подслойным способом Пожаровзрывобезопасность Fire and Explosion Safety. -2014. -Т. 23, № 6. -С. 76-80.


Review

For citations:


Melnikov A.I. Influence of interfacial tension on flow rate and specific consumption of fluorinated foaming agent, containing added ammonium chloride. Pozharovzryvobezopasnost/Fire and Explosion Safety. 2018;27(2-3):93-98. (In Russ.) https://doi.org/10.18322/PVB.2018.27.02-03.93-98

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