Preview

Pozharovzryvobezopasnost/Fire and Explosion Safety

Advanced search
Open Access Open Access  Restricted Access Subscription Access

Influence of dispersed water on combustion characteristics of gaseous mixtures

https://doi.org/10.22227/0869-7493.2026.35.03.13-26

Abstract

Introduction. The combustion characteristics of gaseous mixtures in water sprays are analyzed. The relevance of this study is attributable to the wider use of dispersed water to reduce the explosion hazard associated with accidental releases of flammable gases. The aim of this work is to provide an analytical review of studies on the influence of dispersed water on the explosion characteristics of flammable gaseous mixtures.

Analysis of studies addressing the phlegmatizing effect of dispersed water. Droplet size is shown to be the key parameter determining the phlegmatizing effect of dispersed water. Phlegmatization is observed at droplet sizes below 20–30 µm. Phlegmatization reduces the maximum explosion pressure, the explosion pressure rise rate, and the normal burning velocity. However, complete phlegmatization is generally attainable only for near-limit mixtures. Water droplets with diameters up to 1,000 µm can be used to suppress gaseous detonation due to the fragmentation of large droplets in a shock wave.

Analysis of studies reporting the combustion-promoting effect of dispersed water. Combustion intensification was observed under the action of water droplets larger than 50 µm; this effect was accompanied by flame acceleration and more complete combustion. In some cases, combustion-to-detonation transition can occur.

Conclusions. Based on the analysis performed, conditions are identified under which dispersed water can intensify or suppress the combustion of gaseous mixtures.

About the Author

Yu. N. Shebeko
All-Russian Research Institute for Fire Protection of Ministry of Russian Federation for Civil Defense, Emergencies and Elimination of Consequences of Natural Disasters
Russian Federation

Yury N. SHEBEKO, Dr. Sci. (Eng.), Professor, Chief Researcher

VNIIPO, 12, Balashikha, Moscow Region, 143903

RSCI AuthorID: 47042, Scopus: 7006511704



References

1. Medvedev S.P., Gelfand B.E., Polenov A.N., Khomic S.V. Combustion limits of hydrogen-air mixtures in the concept of ultradispersed water droplets (fog). Combustion, Explosion and Shock Waves. 2002; 38(4):3-8. EDN ONTMZL. (rus).

2. Popov O.E., Kusharin A.Yu., Agafonov G.L., Gelfand B.E. On the phlegmatization of combustion of hydrogen-air mixtures containing water vapor and water aerosol. High Temperature. 2002; 40(5):790-794. URL: https://energy.ihed.ras.ru/arhive/article/1953 (rus).

3. Korolchenko A.Ya., Shebeko Yu.N., Trunev A.V., Navzenya V.Yu., Papkov S.N., Zeitsev A.A. The influence of aerosol forming during rapid evaporation of overheated water on combustion of methane-air mixtures in a closed vessel. Physics of Combustion and Explosion, Explosion and Shock Waves. 1995; 32(2):17-22. EDN KTCDXH. (rus).

4. Tsai S.S., Liparulo N.J. Fog inerting criteria for hydrogen-air mixtures. Proceedings of the 2nd International Conference on Hydrogen Impact on Water Reactor Safety. NUREC/CP 0038. Albuquerque, NM, 1982; 727-739. URL: https://www.nrc.gov/docs/ML1732/ML17320A793.pdf

5. Shebeko Yu.N., Korolchenko A.Ya., Trunev A.V., Navzenya V.Yu., Zaitsev A.A. The influence of a superheated water aerosol on flammability limits and laminar burning velocities of a premixed methane-air flame. Proceedings of the First International Seminar on Fire and Explosion Hazard of Substances and Venting of Deflagrations. Moscow, 1995; 362-365.

6. Navtsenya V.Yu. Development of scientific foundations and improvement of methods for ensuring fire and explosion safety of technological equipment with flammable gases and liquids : abstract of the dissertation of Doctor of Technical Sciences. Moscow, All-Russian Scientific Research Institute of Fire Defence of the Ministry of Civil Defense, Emergencies and Elimination of Consequences of Natural Disasters of the Russian Federation, 2003; 47. EDN NJPEJJ. (rus).

7. Bezrodniy I.F., Starenkov A.N. Highly efficient method of extinguishing fires with aerosol by water spray. Fire safety, information technology and engineering. 1993; 1(3):72-74. (rus).

8. Ingram J.M., Averill A.F., Battersby P.N., Holborn P.G., Nolan P.F. Suppression of hydrogen-oxygen-nitrogen explosions by fine water mist: Part 1. Burning velocity. International Journal of Hydrogen Energy. 2012; 37:19250-19257. DOI: 10.1016/j.ijhydene.2012.09.092. EDN ROUBST.

9. Battersby P.N., Averill A.F., Ingram J.M., Holborn P.G., Nolan P.F. Suppression of hydrogen-oxygen-nitrogen explosions by fine water mist: Part 2. Mitigation of vented deflagrations. International Journal of Hydrogen Energy. 2012; 37:19258-19267. DOI: 10.1016/j.ijhydene.2012.10.029

10. Gai G., Kudriakov S., Roggy B., Hadjadj A., Studer E., Tomine O. Numerical study of laminar burning velocity of hydrogen-air combustion under water spray effects. International Journal of Hydrogen Energy. 2019; 44:17015-17029. DOI: 10.1016/j.ijhydene.2019.04.225

11. Holborn P.G., Battersby P.N., Ingram J.M., Averill A.F., Nolan P.F. Modeling the effect of water fog on the upper flammability limit of hydrogen-oxygen-nitrogen mixtures. International Journal of Hydrogen Energy. 2013; 38(16):6896-6903. DOI: 10.1016/j.ijhydene.2013.03.091. EDN RRHFQH.

12. Jones S.R., Averill A.F., Ingram J.M., Holborn P.G., Battersby P.N., Nolan P.F. et al. Mitigation of hydrogen-air explosion using fine water mist spray. Institution of Chemical Engineers Symposium Series. 2006; 440-447. URL: https://www.icheme.org/media/9816/xix-paper-28.pdf

13. Wen X., Wang M., Su T., Zhang S., Pan R., Ji W. Suppression effects of ultrafine water mist on hydrogen/methane mixture explosion in an obstructed chamber. International Journal of Hydrogen Energy. 2019; 44(60):32332-32342. DOI: 10.1016/j.ijhydene.2019.10.110

14. Fuss S.P., Chen E.F., Yang W., Kee R.J., Williams B.A., Fleming J.W. Inhibition of premixed methane/air flames by water mist. Proceedings of the Combustion Institute. 2002; 29(1):361-368. DOI: 10.1016/s1540-7489(02)80048-7. EDN VGUDUT.

15. Xia Y., Zhang B., Zhang J., Wang B., Chen L., Wang R. et al. Experimental research on combined effect of obstacle and local spraying water fog on hydrogen/air premixed explosion. International Journal of Hydrogen Energy. 2022; 47(94):40099-40115. DOI: 10.1016/j.ijhydene.2022.09.152. EDN DDPXYN.

16. Boeck L.R., Kink A., Oezdin D., Hasslberger J., Sattelmayer T. Influence of water mist on flame acceleration, DDT and detonation. International Journal of Hydrogen Energy. 2015; 40(21):6995-7004. DOI: 10.1016/j.ijhydene.2015.03.129

17. Butz J., French P., Plooster M. Application of fine water mist to hydrogen deflagrations. Proceedings of Halon Options Technical Conference. Albuquerque, NM, 1993; 345-355. URL: ystem/files/documents/el/fire_research/R9302947.pdf

18. Song Y., Zhang Q. Quantitative research on gas explosion inhibition by water mist. Journal of Hazardous Materials. 2019; 363:16-25. DOI: 10.1016/j.jhazmat.2018.09.059

19. Thomas G.O., Edwards M.J., Edwards D.H. Studies of detonation quenching by water sprays. Combustion Science and Technology. 1990; 71(4-6):233-245. DOI: 10.1080/001022090089951634

20. Pei B., Yang Y., Li J., Yu M. Experimental study of suppression effect of inert gas two fluid water mist system on methane explosion. Procedia Engineering. 2018; 211:565-574. DOI: 10.1016/j.proeng.2017.12.049

21. Zhang P., Zhou Y., Cao X., Bi M. Mitigation of methane-air explosion in a closed vessel by ultrafine water fog. Safety Science. 2014; 62:1-7. DOI: 10.1016/j.ssci.2013.07.027. EDN RISSML.

22. Bekele A.G., Zhang B., Xia Y., Wang B., Siqi Z., Yue W. Experimental study of the characteristics of premixed methane/hydrogen deflagration and water mist suppression in a semi-confined duct. Case Study in Thermal Engineering. 2025; 72:106280. DOI: 10.1016/j.csite.2025.106280

23. Yoshida A., Okawa T., Ebina W., Naito H. Experimental and numerical investigation of flame speed retardation by water mist. Combustion and Flame. 2015; 162(5):1772-1777. DOI: 10.1016/j.combustflame.2014.11.038. EDN VGUDYF.

24. Nakamura K., Yoshida A., Nishioka M. Experimental and numerical simulation on the suppression of explosion of propane/air mixture by water mist. Combustion and Flame. 2021; 223:192-201. DOI: 10.1016/j.combustflame.2020.09.014. EDN LVXYPA.

25. Thomas G.O. On the conditions required for explosion mitigation by water sprays. Transactions of the Institute of Chemical Engineers. 2000; 78(5):339-354. URL: 10.1205/095758200530862

26. Brenton J.R., Thomas G.O. Small-scale studies of water spray dynamics during explosion mitigation tests. Institution of Chemical Engineers Symposium Series N134: Hazard XII. 1994; 393-403. URL: https://www.icheme.org/media/10388/xii-paper-27.pdf

27. Van Wingerden K., Wilkins B. The influence of water sprays on gas explosions. Part 1: Water spray generated turbulence. Journal of Loss Prevention in the Process Industries. 1995; 8(2):53-59. DOI: 10.1016/0950-4230(95)00002-I

28. Thomas G.O., Jones A., Edwards M.J. Influence of water sprays on explosion development in fuel-air mixtures. Combustion Science and Technology. 1991; 80(1-3):47-61. DOI: 10.1080/00102209108951776

29. Gieras M. Flame acceleration due to water droplet action. Journal of Loss Prevention in the Process Industries. 2008; 21:472-477. DOI: 10.1016/j.jlp.2008.03.004

30. Shebeko Yu.N., Tsarichenko S.G., Eremenko O.Ya., Keller V.D., Trunev A.V. Combustion of lean hydrogen-air mixtures in a flow of atomized water. Physics of Combustion and Explosion. 1990; 26(4):58-61. URL: https://sibran.ru/journals/issue.php?ID=120139&ARTICLE_ID=135334 (rus).

31. Tsarichenko S.G., Trunev A.V., Shebeko Yu.N., Nikolaev L.A., Belyaev V.V. Intensification of combustion processes of hydrogen-air mixtures in a flow of sprayed water. Questions of atomic science and technology. Series: Nuclear engineering and technology. Issue 1. 1991; 48-50. (rus).

32. Makeev V.I., Ponomarev A.A., Strogonov V.V. Features of combustion and transition to detonation of gas mixtures when irrigated with water. Problems of combustion and explosion : Proceedings of the IX All-Union Symposium on combustion and explosion. Chernogolovka, 1989; 50-53. (rus).

33. Zhang P., Zhou Y., Cao Y., Cao X., Bi M. Enhancement effects of methane/air explosion caused by water spraying in a sealed vessel. Journal of Loss Prevention in the Process Industries. 2014; 29:313-318. DOI: 10.1016/j.jlp.2014.03.014

34. Wang F., Yu M., Wen X., Deng H., Pei B. Suppression of methane/air explosion in pipeline by water mist. Journal of Loss Prevention in the Process Industries. 2017; 49(B):791-796. DOI: 10.1016/j.jlp.2017.02.005

35. Xia Y., Zhang B., Wang B., Zhang S., Yue W., Zhang J. Inhibition effect and mechanism of micro-sized water mist containing dimethyl methylphosphonate in hydrogen explosions. International Journal of Hydrogen Energy. 2025; 140:594-607. DOI: 10.1016/j.ijhydene.2025.05.228. EDN LRLRHQ.

36. Zhao X., Zhao J., Zhu X., Xu X., Zhang G., Wang Ch. et al. Study on the supporession of hydrogen-air explosions by ultrafine water mist containing KCl, K2CO3, or NaCl. Fire Safety Journal. 2025; 153:104356. DOI: 10.1016/j.firesaf.2025.104356. EDN UFMASK.

37. Yang Y., Cen K., Duan Y., Mi H., Xi G., Wang S. Comparable experimental study on inhibition of hydrogen/methane/air explosion by water mist containing different additives. International Journal of Hydrogen Energy. 2026; 204:153236. DOI: 10.1016/j.ijhydene.2025.153236. EDN QVJCUW.

38. Cui Y., Liu J. Research progress of water mist fire extinguishing technology and its application in battery fires. Process Safety and Environmental Protection: Transactions of the institution of chemical engineers, part B. 2021; 149:559-574. DOI: 10.1016/j.psep.2021.03.003. EDN NWPPFZ.

39. Cao X., Zhou Y., Wang Z., Fan L., Wang Zh. Experimental research on hydrogen/air explosion inhibition by the ultrafine water mist. International Journal of Hydrogen Energy. 2022; 47(56):23898-23908. DOI: 10.1016/j.ijhydene.2022.05.165. EDN FTATJB.

40. Pei B., Xu T., Zhou L., Han Y., Lv H., Song W. et al. The inhibition of CO2 twin-fluid water mist with modified inorganic salt on LPG explosion: Experimental tests and simulations. Energy. 2025; 335:138235. DOI: 10.1016/j.energy.2025.138235. EDN BVZXXE.

41. Zhao J., Pan Ch., Zhu X., Yu J., Cheng K., Wang X. Study on the suppression of methane/hydrogen/air explosions by water mist containing a BmimBF4 additive. International Journal of Hydrogen Energy. 2015; 40:6995-7004. DOI: 10.1016/j.ijhydene.2025.06.064. EDN HERTKA.

42. Zhang Z., Yang Ke., Du X., Ji D., Ji H., Jiang Ju. Comparative experimental study on inhibition of methane explosion by ultrafine water mist containing different additives. Journal of Loss Prevention in the Process Industries. 2025; 96:105607. DOI: 10.1016/j.jlp.2025.105697. EDN TUBGGW.

43. Badhuk P., Ravikrishna R.V. Flame inhibition by aqueous solution of Alkali salts in methane and LPG laminar diffusion flames. Fire Safety Journal. 2022; 130:103586. DOI: 10.1016/j.firesaf.2022.103586. EDN IUSPUI.

44. Lui L., Luo Zh., Yang Y., Wang T., Su B., Zhou Sh. et al. Suppression performance and mechanism of water mist containing compound potassium salts on hydrogen-enriched natural gas jet flame. International Journal of Hydrogen Energy. 2025; 113:646-654. DOI: 10.1016/j.ijhydene.2025.03.023. EDN JFJMFS.

45. Lu Ch., Wei D., Chen M., Lui B., Wang J., Pan R. et al. Effect of water mist with composite additives on mitigation thermal runaway in lithium-ion batteries: A study of suppression timing and mechanism. Journal of Energy Storage. 2026; 162:122137. DOI: 10.1016/j/est.2026.122137

46. Deng Ju., Ren X., Li Ya., Zhang Yu., Zhang Yu. Analysis of the effectiveness and mechanism of fine water mist fire suppression using NaF, NaCl, and NaBr additives. Process Safety and Environmental Protection. 2026; 208:108459. DOI: 10.1016/j.psep.2026.108459


Review

For citations:


Shebeko Yu.N. Influence of dispersed water on combustion characteristics of gaseous mixtures. Pozharovzryvobezopasnost/Fire and Explosion Safety. 2026;35(3):13-26. (In Russ.) https://doi.org/10.22227/0869-7493.2026.35.03.13-26

Views: 43

JATS XML

ISSN 0869-7493 (Print)
ISSN 2587-6201 (Online)