Investigation of toxicity parameters of combustion products of upholstered furniture elements
https://doi.org/10.22227/0869-7493.2024.33.01.51-59
Abstract
Introduction. Upholstered furniture occupies quite a significant area of the premises of many public buildings. During its combustion, mixtures of toxic gases can be formed, the quantitative and qualitative composition of which is unknown. Therefore, obtaining experimental data on the toxicity of upholstered furniture is an urgent task.
Goals and objectives. Experimental determination of flammability and toxicity parameters of combustion products of upholstered furniture elements necessary for calculation of the time of blocking of evacuation routes in buildings.
To achieve this, experimental studies of specimens of upholstered furniture elements were carried out on standard installations, as well as on the installation for determining the fire hazard of condensed substances and materials.
Research methods. Standard methods for determining the flammability of decorative fabrics (GOST R 50810–95), the flammability of upholstered furniture elements (GOST R 53294–2009), the toxicity index of combustion products (GOST 12.1.044.89, paragraph 4.20) and the method for assessing toxic gas concentrations at a small-scale experimental installation to determine the fire hazard of condensed substances and materials were used.
Research results and their discussion. The determination of flammability of materials and compositions of upholstered furniture products, as well as the assessment of the toxicity of the gaseous atmosphere during their thermal decomposition in a small-scale experimental installation allowing the measurement of concentrations of toxic gases, were performed. Experimental studies were carried out to study the toxicity parameters of the most dangerous gases formed during the combustion of a number of specimens of upholstered furniture elements.
It was revealed that during the combustion of upholstered furniture elements, such highly toxic gases as hydrogen cyanide and carbon monoxide are emitted in concentrations dangerous to human life and health.
Conclusions. New experimental data on specific mass rate of burnout velocity, as well as numerical values of specific coefficients of carbon monoxide and hydrogen cyanide formation of upholstered furniture elements have been obtained, which will allow to expand the existing database of typical fire load in building premises.
About the Authors
S. V. PuzachRussian Federation
Sergey V. PUZACH, Dr. Sci. (Eng.), Professor, the Honoured Scientist of the Russian Federation, Professor of Department of Integrated Safety in Construction
Yaroslavskoe shosse, 26, Moscow, 129337
Scopus AuthorID: 7003537835; ResearcherID: U-2907-2019
N. I. Konstantinova
Russian Federation
Nataliya I. KONSTANTINOVA, Dr. Sci. (Eng.), Professor, Chief Researcher
VNIIPO, 12, Balashikha, Moscow Region, 143903
ID RSCI: 774306
R. G. Akperov
Russian Federation
Ruslan G. AKPEROV, Cand. Dci. (Eng.), Assistant Professor of Thermal Physics and Hydraulic Department
Borisa Galushkina St., 4, Moscow, 129366
A. O. Ovchinnikov
Russian Federation
Alexsandr O. OVCHINNIKOV, Undergraduate
Borisa Galushkina St., 4, Moscow, 129366
References
1. Puzach S.V., Doan V.M., Nguen T.D., Sulejkin E.V., Akperov R.G. Formation, distribution and human exposure to toxic combustion products during a fire in a room. Moscow, State Fire Academy of Emercom of Russia Publ., 2017; 130. (rus).
2. Puzach S.V., Boldrushkiev O.B. Determination of the specific coefficient of formation and critical partial density of hydrogen cyanide and carbon monoxide during a fire in a room. Pozharovzryvobezopasnost’/Fire and explosion safety. 2019; 28(5):19-26. DOI: 10.18322/PVB.2019.28.05.19-26 (rus).
3. Konstantinova N.I., Zuban A.V., Bulgakova A.A. Improving the methodological approach to assessing the fire hazard of mattresses. Pozharovzryvobezopasnost/Fire and Explosion Safety. 2022; 31(2):22-32. DOI: 10.22227/0869-7493.2022.31.02.22-32 (rus).
4. Konstantinova N.I., Erofeev O.O. Development of materials for upholstered furniture elements of reduced fire hazard. Fibre Chemistry. 2022; 54:258-262. DOI: 10.1007/s10692-023-10389-8
5. Thomas T., Babich M.A. CPSC staff exposure and risk assessment of flame retardant chemicals in residential upholstered furniture. U.S. Consumer Product Safety Commission. 2015; 109. DOI: 10.13140/RG.2.1.3291.6646
6. Storesund K., Steen-Hansen A., Bergstrand A. Fire safe upholstered furniture Alternative strategies to the use of chemical flame retardants. REPORT. 2015; A15 20124(2):48. DOI: 10.13140/RG.2.2.15431.70564
7. Puzach S.V., Konstantinova N.I., Akperov R.G., Ovchinnikov A.O. Fire hazard of upholstered furniture elements. Roitman readings : collection of materials of the XI scientific and practical conference. D.A. Samoshin (Ed.). Moscow, 2023; 70-74.
8. Fabian T.Z., Gandhi P.D. Upholstered furniture flammability: Full-scale furniture and flashover experiments. Conference: Fire & Materials. 2013; 1-11.
9. Zammarano M., Hoehler M.S., Shields J.R., Thompson A.L., Kim I., Leventon I.T. et al. Bundy Full-Scale Experiments to Demonstrate Flammability Risk of Residential Upholstered Furniture and Mitigation Using Barrier Fabric. National Institute of Standards and Technology, 2020. DOI: 10.1177/0734904114543450
10. Nasare S., Pitts W., Matko S., Davis R.D. Evaluating smoldering behavior of barrier fabrics. Journal of Fire Sciences. 2014; 32(6):539-562. DOI: 10.1177/0734904114543450
11. Davis A., Ryan P.B., Cohen J.A., Harris D., Black M. Chemical exposures from upholstered furniture with various flame retardant technologies. Indoor air. 2021; 31(5):1473-1483. DOI: 10.1111/ina.12805
12. Puzach S.V., Bachurin D.V., Akperov R.G., Boldrushkiev О.B., Balaev A.A. Generation of toxic gases during combustion of stuffed toys in multifunction shopping malls. Pozharovzryvobezopasnost/Fire and Explosion Safety. 2023; 32(1):41-50. DOI: 10.22227/0869-7493.2023.32.01.41-50 (rus).
13. Puzach S.V., Boldrushkiev O.B., Akperov R.G. The need to take into account the combined effects of harmful combustion products when determining the time of blocking escape routes. Roitman readings : collection of materials from the 10th scientific and practical conference (Moscow, May 26, 2022). 2022; 96-99. (rus).
14. Jakobsen J., Babigumira R., Danielsen M., Grimsrud T.K., Olsen R., Rosting C. et al. Work conditions and practices in Norwegian fire departments from 1950 until today: a survey on factors potentially influencing carcinogen exposure. Safety and Health at Work. 2020; 11(4):509-516. DOI: 10.1016/j.shaw.2020.07.004
15. Wang S., Huang D., Guo C., Yuan Q., Chen Y., Lin P., Duan P. Bottom fire ehaviour of thermally thick natural rubber latex foam. E-Polymers. 2019; 19(1):9-14. DOI: 10.1515/epoly-2019-0002
16. Pauluhn J. Phosgene inhalation toxicity: Update on mechanisms and mechanism-based treatment strategies. Toxicology. 2021; 450:152682. DOI: 10.1016/j.tox.2021.152682
17. Kaczorek-Chrobak K., Fangrat J. PVC-based copper electric wires under various fire conditions: toxicity of fire effluents. Materials. 2020; 13(5):1111. DOI: 10.3390/ma13051111
18. Pauluhn J. Acute inhalation toxicity of carbon monoxide and hydrogen cyanide revisited: Comparison of models to disentangle the concentration × time conundrum of lethality and incapacitation. Regulatory Toxicology and Pharmacology. 2016; 80:173-182. DOI: 10.1016/j.yrtph.2016.06.017
Review
For citations:
Puzach S.V., Konstantinova N.I., Akperov R.G., Ovchinnikov A.O. Investigation of toxicity parameters of combustion products of upholstered furniture elements. Pozharovzryvobezopasnost/Fire and Explosion Safety. 2024;33(1):51-59. (In Russ.) https://doi.org/10.22227/0869-7493.2024.33.01.51-59