<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">firesmi</journal-id><journal-title-group><journal-title xml:lang="ru">Пожаровзрывобезопасность/Fire and Explosion Safety</journal-title><trans-title-group xml:lang="en"><trans-title>Pozharovzryvobezopasnost/Fire and Explosion Safety</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0869-7493</issn><issn pub-type="epub">2587-6201</issn><publisher><publisher-name>ФГБОУ ВО «Национальный исследовательский Московский государственный строительный университет»</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.18322/PVB.2017.26.09.15-28</article-id><article-id custom-type="elpub" pub-id-type="custom">firesmi-82</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ПРОЦЕССЫ ГОРЕНИЯ, ДЕТОНАЦИИ И ВЗРЫВА</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>COMBUSTION, DETONATION AND EXPLOSION PROCESSES</subject></subj-group></article-categories><title-group><article-title>О взрывоопасности аэровзвеси меламина</article-title><trans-title-group xml:lang="en"><trans-title>On explosibility of melamine dust/air mixture</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Полетаев</surname><given-names>Н. Л.</given-names></name><name name-style="western" xml:lang="en"><surname>Poletaev</surname><given-names>N. L.</given-names></name></name-alternatives><email xlink:type="simple">nlpvniipo@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff xml:lang="ru" id="aff-1"><institution>ВНИИПО МЧС России</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2017</year></pub-date><pub-date pub-type="epub"><day>05</day><month>04</month><year>2018</year></pub-date><volume>26</volume><issue>9</issue><fpage>15</fpage><lpage>28</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Полетаев Н.Л., 2018</copyright-statement><copyright-year>2018</copyright-year><copyright-holder xml:lang="ru">Полетаев Н.Л.</copyright-holder><copyright-holder xml:lang="en">Poletaev N.L.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.fire-smi.ru/jour/article/view/82">https://www.fire-smi.ru/jour/article/view/82</self-uri><abstract><p>Дан анализ особенностей опасности пыли, максимальное давление взрыва аэровзвеси которой Pmax сопоставимо с величиной 100 кПа. Предложено такую пыль считать пылью с низкой взрывоопасностью в отличие от пыли с высокой взрывоопасностью, у аэровзвеси которой Pmax &gt;&gt; 100 кПа. Показано, что для пыли с низкой взрывоопасностью минимальное взрывоопасное содержание кислорода (LOC) близко к содержанию кислорода в атмосфере COX,0 = (20,7±0,1) % об., и для оценки взрывоопасности такой пыли разумно, наряду с нормативным параметром Pmax, использовать параметр DOX = COX,0 - LOC. Для пыли с низкой взрывоопасностью 0 &lt; DOX &lt; 0,5 % об. Иллюстрацию результатов работы проводили с использованием известных данных исследования в 20-л и 1000-л камерах взрывоопасности аэровзвесей трех образцов меламина со средним размером частиц dm менее 10, 19 и 52 мкм соответственно. Показано, что взвеси всех рассмотренных образцов меламина в атмосферном воздухе являются невзрывоопасными при нормальных условиях (абсолютном давлении P0 = 100 кПа, температуре T0 = 25 °С). Поскольку исследование пыли в 20-л камере фактически производится при повышенных начальных значениях температуры и давления (Полетаев, 2017), удалось определить, что нагрев невзрывоопасной аэровзвеси образца меламина с dm = 19 мкм до 68 °С заведомо переводит ее в аэровзвесь с высокой взрывоопасностью. Показано также, что для невзрывоопасной аэровзвеси, у которой LOC » COX,0, аналогичный переход возможен при нагреве всего на 10…20 °С.</p></abstract><trans-abstract xml:lang="en"><p>The work is mainly devoted to the analysis of dust hazard features, whose test in a standard blasting chamber with a volume of 20 liters to 1 m3 leads to a maximum pressure Pmax comparable to a value of 100 kPa. Such dust is suggested to be considered dust with a low explosion hazard, in contrast to dust with high explosion hazard ( Pmax &gt;&gt; 100 kPa). The choice of the critical pressure level (»100 kPa), indicating the flame propagation over a considerable distance from the ignition source, is based on the analogy between the models of percolation theory and the simplified combustion scheme for a macroscopically inhomogeneous dust/air mixture. For dust with low explosion hazard (Poletaev, 2017), the limiting oxygen concentration (LOC) is close to the normal oxygen content in the atmosphere COX,0 = (20.7 ± 0.1) % by vol. It was proposed to use the parameter DOX = COX,0 - LOC to evaluate the dust explosion hazard along with the standard parameter Pmax. It is shown that for dust with a low explosion hazard 0 &lt; DOX &lt; 0.5 % by vol. An illustration of the conclusions of the work was carried out using the known results of a study in 20-l and 1000-l blasting chambers of three melamine samples with an average particle size dm of less than 10, 19 and 52 μm, respectively. It is shown that the mixtures of all the examined melamine samples with atmospheric air are non-explosive under normal conditions (absolute pressure 100 kPa, temperature 25 °C). To explain the non-explosive of melamine dust having a high calorific value (15.67 MJ/kg), it has been suggested that the volatile component of its thermal decomposition products (ammonia) is burned, which allows an analogy between the combustion of melamine and coal particles. On the basis of the fact that a study of dust in a 20-liter chamber is actually performed at elevated initial values of temperature and pressure (Cashdollar and Chatrathi, 1993, Poletaev, 2017), the temperature at which a melamine sample ( dm = 19 μm) forms dust/air mixture with a high explosive hazard was determined (68 °C). The importance of this result is due to the fact that in the production of dispersed melamine, the finished product can be transported by air with a temperature of over 100 °C. In European standards EN 14034, the correction of the value of Pmax obtained in a 20-liter chamber is proposed with the aim of predicting the value of this parameter, expected from the results of tests in a 1000-liter chamber. The above test feature in a 20-liter chamber makes such an adjustment erroneous in the case of dust with low explosion hazard. Taking into account this peculiarity and a number of empirical regularities of turbulent combustion of an dust/air mixture, an estimate of the minimum value of the index Kst , corresponding to the case of an explosion in a 20-liter chamber, is performed. It is shown that for a subcritical non-explosive dust/air mixture (LOC » COX,0) the transition to a state of high explosion hazard is possible with heating by only 10…20 °C.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>взрыв пыли</kwd><kwd>критерий взрыва</kwd><kwd>низкая взрывоопасность</kwd><kwd>высокое LOC</kwd><kwd>меламин</kwd><kwd>dust explosion</kwd><kwd>explosion criterion</kwd><kwd>low explosibility</kwd><kwd>high LOC</kwd><kwd>melamine</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">NFPA 654. Standard for the prevention of fire and dust explosions from the manufacturing, processing, and handling of combustible particulate solids.-2017 Edition.-Quincy, Massachusetts : National Fire Protection Association, 2012.-72 p.</mixed-citation><mixed-citation xml:lang="en">NFPA 654. Standard for the prevention of fire and dust explosions from the manufacturing, processing, and handling of combustible particulate solids.-2017 Edition.-Quincy, Massachusetts : National Fire Protection Association, 2012.-72 p.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">EN14034-1:2004+A1:2011. Determination of explosion characteristics of dust clouds-Part 1: Determination of the maximum explosion pressure pmax of dust clouds.-European Committee for Standardisation (CEN), 2011.-30 p.</mixed-citation><mixed-citation xml:lang="en">EN14034-1:2004+A1:2011. Determination of explosion characteristics of dust clouds-Part 1: Determination of the maximum explosion pressure pmax of dust clouds.-European Committee for Standardisation (CEN), 2011.-30 p.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">EN14034-2:2006+A1:2011. Determination of explosion characteristics of dust clouds-Part 2: Determination of the maximum rate of explosion pressure rise (dp/dt)max of dust clouds.-European Committee for Standardisation (CEN), 2011.-30 p.</mixed-citation><mixed-citation xml:lang="en">EN14034-2:2006+A1:2011. Determination of explosion characteristics of dust clouds-Part 2: Determination of the maximum rate of explosion pressure rise (dp/dt)max of dust clouds.-European Committee for Standardisation (CEN), 2011.-30 p.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">EN14034-3:2006+A1:2011. Determination of explosion characteristics of dust clouds-Part 3: Determination of the lower explosion limit LEL of dust clouds.-European Committee for Standardisation (CEN), 2011.-30 p.</mixed-citation><mixed-citation xml:lang="en">EN14034-3:2006+A1:2011. Determination of explosion characteristics of dust clouds-Part 3: Determination of the lower explosion limit LEL of dust clouds.-European Committee for Standardisation (CEN), 2011.-30 p.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">EN14034-4:2004+A1:2011. Determination of explosion characteristics of dust clouds-Part 4: Determination of the limiting oxygen concentration LOC of dust clouds.-European Committee for Standardisation (CEN), 2011.-30 p.</mixed-citation><mixed-citation xml:lang="en">EN14034-4:2004+A1:2011. Determination of explosion characteristics of dust clouds-Part 4: Determination of the limiting oxygen concentration LOC of dust clouds.-European Committee for Standardisation (CEN), 2011.-30 p.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">ASTM E1515-14. Standard test method for minimum explosible concentration of combustible dusts. -West Conshohocken, PA : ASTM International, 2014. -9 p. DOI: 10.1520/E1515-14.</mixed-citation><mixed-citation xml:lang="en">ASTM E1515-14. Standard test method for minimum explosible concentration of combustible dusts. -West Conshohocken, PA : ASTM International, 2014. -9 p. DOI: 10.1520/E1515-14.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">ASTM E1226-12a. Standard test method for explosibility of dust clouds.-West Conshohocken, PA: ASTM International, 2012.-13 p. DOI: 10.1520/E1226-12A.</mixed-citation><mixed-citation xml:lang="en">ASTM E1226-12a. Standard test method for explosibility of dust clouds.-West Conshohocken, PA: ASTM International, 2012.-13 p. DOI: 10.1520/E1226-12A.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Brenn- und Explosions-KenngrцЯen von Stдuben / Scholl E. W., Reeh D., Wiemann W. u. a. // SFTReport. -1979.-No. 2.2. -100 s. (in German).</mixed-citation><mixed-citation xml:lang="en">Brenn- und Explosions-KenngrцЯen von Stдuben / Scholl E. W., Reeh D., Wiemann W. u. a. // SFTReport. -1979.-No. 2.2. -100 s. (in German).</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Hertzberg M., Cashdollar K. L., Zlochower I. A. Flammability limit measurements for dusts and gases: Ignition energy requirements and pressure dependences // Symposium (International) on Combustion. -1988. -Vol. 21, Issue 1. -Р. 303-313. DOI: 10.1016/S0082-0784(88)80258-3.</mixed-citation><mixed-citation xml:lang="en">Hertzberg M., Cashdollar K. L., Zlochower I. A. Flammability limit measurements for dusts and gases: Ignition energy requirements and pressure dependences // Symposium (International) on Combustion. -1988. -Vol. 21, Issue 1. -Р. 303-313. DOI: 10.1016/S0082-0784(88)80258-3.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Proust Ch., Accorsi A., Dupont L. Measuring the violence of dust explosions with the “20l sphere” and with the standard “ISO 1 m3 vessel”: Systematic comparison and analysis of the discrepancies // Journal of Loss Prevention in the Process Industries. - Vol. 20, Issue 4-6. - P. 599-606. DOI: 10.1016/j.jlp.2007.04.032.</mixed-citation><mixed-citation xml:lang="en">Proust Ch., Accorsi A., Dupont L. Measuring the violence of dust explosions with the “20l sphere” and with the standard “ISO 1 m3 vessel”: Systematic comparison and analysis of the discrepancies // Journal of Loss Prevention in the Process Industries. - Vol. 20, Issue 4-6. - P. 599-606. DOI: 10.1016/j.jlp.2007.04.032.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Полетаев Н. Л. О проблеме экспериментального обоснования низкой взрывоопасности горючей пыли в 20-литровой камере // Пожаровзрывобезопасность / Fire and Explosion Safety.-2017. -Т. 26, №6. -С. 5-20. DOI: 10.18322/PVB.2017.26.06.5-20.</mixed-citation><mixed-citation xml:lang="en">Полетаев Н. Л. О проблеме экспериментального обоснования низкой взрывоопасности горючей пыли в 20-литровой камере // Пожаровзрывобезопасность / Fire and Explosion Safety.-2017. -Т. 26, №6. -С. 5-20. DOI: 10.18322/PVB.2017.26.06.5-20.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Eckhoff R. K. Dust explosions in the process industries.-3rd edition.-Boston : Elsevier Science, Gulf Professional Publishing, 2003.-720 p.</mixed-citation><mixed-citation xml:lang="en">Eckhoff R. K. Dust explosions in the process industries.-3rd edition.-Boston : Elsevier Science, Gulf Professional Publishing, 2003.-720 p.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Haynes W. M. (ed.). CRC Handbook of Chemistry and Physics.-95 edition.-CRC Press, 2014.- P. 3-516.</mixed-citation><mixed-citation xml:lang="en">Haynes W. M. (ed.). CRC Handbook of Chemistry and Physics.-95 edition.-CRC Press, 2014.- P. 3-516.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">ISO/IEC 80079-20-2:2016. Explosive atmospheres-Part 20-2: Material characteristics-Combustible dusts test methods. -1st edition. -Geneva, Switzerland : ISO/IEC, 2016. -100 p.</mixed-citation><mixed-citation xml:lang="en">ISO/IEC 80079-20-2:2016. Explosive atmospheres-Part 20-2: Material characteristics-Combustible dusts test methods. -1st edition. -Geneva, Switzerland : ISO/IEC, 2016. -100 p.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Morton J. S. The synthesis, reduction, and decomposition of novel high-nitrogen bis s-triazinyl hydrazines and diazines : Dr. chem. sci. diss. -University of Rhode Island, 2008.</mixed-citation><mixed-citation xml:lang="en">Morton J. S. The synthesis, reduction, and decomposition of novel high-nitrogen bis s-triazinyl hydrazines and diazines : Dr. chem. sci. diss. -University of Rhode Island, 2008.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Тарасевич Ю.Ю. Перколяция: теория, приложения, алгоритмы : учебное пособие.-М. : Едиториал УРСС, 2002.-113 с.</mixed-citation><mixed-citation xml:lang="en">Тарасевич Ю.Ю. Перколяция: теория, приложения, алгоритмы : учебное пособие.-М. : Едиториал УРСС, 2002.-113 с.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Institute for Occupational Safety and Health of the German Social Accident Insurance. GESTIS-DUST-EX. URL: http://staubex.ifa.dguv.de/explosuche.aspx.</mixed-citation><mixed-citation xml:lang="en">Institute for Occupational Safety and Health of the German Social Accident Insurance. GESTIS-DUST-EX. URL: http://staubex.ifa.dguv.de/explosuche.aspx.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Glarner T. Temperatureinfluss auf das Explosions- und Zьndverhalten brennbarer Stдube / Dissertation ETHZьrich, Nr. 7350, 1983; Glarner T. Mindestzьndenergie-Einfluss der Temperatur / VDI-Berichte Nr. 494, Seite 109-118, 1984.</mixed-citation><mixed-citation xml:lang="en">Glarner T. Temperatureinfluss auf das Explosions- und Zьndverhalten brennbarer Stдube / Dissertation ETHZьrich, Nr. 7350, 1983; Glarner T. Mindestzьndenergie-Einfluss der Temperatur / VDI-Berichte Nr. 494, Seite 109-118, 1984.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Lipatnikov A. Fundamentals of premixed turbulent combustion.-Boca Raton : CRC Press, Taylor &amp; Francis Group, 2012.-548 p. DOI: 10.1201/b12973.</mixed-citation><mixed-citation xml:lang="en">Lipatnikov A. Fundamentals of premixed turbulent combustion.-Boca Raton : CRC Press, Taylor &amp; Francis Group, 2012.-548 p. DOI: 10.1201/b12973.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Selle Н., Zehr J. Beurteilung der Experimentalwerte fur die untere Zundgreze von Staub / Luft-Gemischen mit Hijfe Thermochemischer Berechnungen.-Staub und Reinhalt Luft, 1954.-Bd. 38.- S. 583 (in German).</mixed-citation><mixed-citation xml:lang="en">Selle Н., Zehr J. Beurteilung der Experimentalwerte fur die untere Zundgreze von Staub / Luft-Gemischen mit Hijfe Thermochemischer Berechnungen.-Staub und Reinhalt Luft, 1954.-Bd. 38.- S. 583 (in German).</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Wiemann W. Influence of temperature and pressure on the explosion characteristics of dust/air and dust/ air/inert gas mixtures // Industrial Dust Explosions / Kenneth L. Cashdollar, Martin Hertzberg (eds.).- Philadelphia : American Society for Testing and Materials, 1987.-P. 33-44. DOI: 10.1520/stp28164s.</mixed-citation><mixed-citation xml:lang="en">Wiemann W. Influence of temperature and pressure on the explosion characteristics of dust/air and dust/ air/inert gas mixtures // Industrial Dust Explosions / Kenneth L. Cashdollar, Martin Hertzberg (eds.).- Philadelphia : American Society for Testing and Materials, 1987.-P. 33-44. DOI: 10.1520/stp28164s.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Cashdollar K. L., Chatrathi K. Minimum explosible dust concentrations measured in 20-l and 1-m3 chambers // Combustion Science and Technology.-1993.-Vol. 87, Issue 1-6.-P. 157--171. DOI: 10.1080/00102209208947213.</mixed-citation><mixed-citation xml:lang="en">Cashdollar K. L., Chatrathi K. Minimum explosible dust concentrations measured in 20-l and 1-m3 chambers // Combustion Science and Technology.-1993.-Vol. 87, Issue 1-6.-P. 157--171. DOI: 10.1080/00102209208947213.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Bartknecht W. Explosionen, ablauf und schutzmaЯnahmen.-Berlin : Springer-Verlag, 1980.-259 s. DOI: 10.1002/cite.330530411.</mixed-citation><mixed-citation xml:lang="en">Bartknecht W. Explosionen, ablauf und schutzmaЯnahmen.-Berlin : Springer-Verlag, 1980.-259 s. DOI: 10.1002/cite.330530411.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Wilйn C., Moilanen A., Rautalin A., Torrent J., Conde E., Lцdel R., Carson D., Timmers P., Brehm K. Safe handling of renewable fuels and fuel mixtures / VTT Publications 394. Espoo : Technical Research Centre of Finland, 1999. - 125 p. URL: http://www.vtt.fi/inf/pdf/publications/1999/P394.pdf (дата обращения: 01.08.2017).</mixed-citation><mixed-citation xml:lang="en">Wilйn C., Moilanen A., Rautalin A., Torrent J., Conde E., Lцdel R., Carson D., Timmers P., Brehm K. Safe handling of renewable fuels and fuel mixtures / VTT Publications 394. Espoo : Technical Research Centre of Finland, 1999. - 125 p. URL: http://www.vtt.fi/inf/pdf/publications/1999/P394.pdf (дата обращения: 01.08.2017).</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
